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Lead(II) oxydiacetate hydrate

Stefan T. Norberg (Institutionen för oorganisk kemi) ; Göran Svensson (Institutionen för oorganisk kemi) ; Jörgen Albertsson (Institutionen för oorganisk kemi)
Acta Crystallographica Section C - Crystal Structure Communications (0108-2701). Vol. 55 (1999), 3, p. 356-358.
[Artikel, refereegranskad vetenskaplig]

The coordination polyhedron around the Pb atom in the title compound, poly[aqualead(II)-mu(5)-oxydiacetato], [Pb(mu(5)-C4H4O5)(H2O)](n), is a distorted square antiprism formed by three O atoms from one oxydiacetate ligand, four O atoms from four other identical ligands and one water O atom, resulting in a three-dimensional network structure. The almost planar oxydiacetate ligand is disordered over two positions. The Pb lone-pair 6s(2) electrons show stereochemical activity in the coordination sphere.

Nyckelord: Coordination Chemistry, Lead Compound, Lone-Pair Electrons, Crystal Structure

Denna post skapades 2009-09-09. Senast ändrad 2010-11-05.
CPL Pubid: 97686


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Institutionen för oorganisk kemi (1900-2003)


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