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Specific features of the structure and electrical conductivity of the magnetically ordered oxide (La0.9Sr0.1)(Fe0.8Mg0.2)O3-y

SA Ivanov ; GM Kaleva ; AV Mosunov ; ED Politova ; Sten G. Eriksson (Institutionen för kemi- och bioteknik, Oorganisk miljökemi ; Institutionen för kemi)
CRYSTALLOGRAPHY REPORTS (1063-7745). Vol. 53 (2008), 1, p. 68-75.
[Artikel, refereegranskad vetenskaplig]

The structure of the (La0.9Sr0.1)(Fe0.8Mg0.2)O-3 (-) (y) oxide is investigated using neutron diffraction at temperatures of 10, 295, 500, 700, and 1000 K. The results of the structure refinement are in good agreement with the experimental data on the electrical conductivity and confirm the inference that the oxidation state of iron cations is higher than 3+ and that the structure of the compound is antiferromagnetically ordered at temperatures below 500 K.

Nyckelord: NEUTRON POWDER DIFFRACTION; ION CONDUCTIVITY; PEROVSKITE OXIDE; DOPED LAGAO3; CERAMICS; TRANSITION



Denna post skapades 2009-05-07. Senast ändrad 2010-01-26.
CPL Pubid: 93645

 

Institutioner (Chalmers)

Institutionen för kemi- och bioteknik, Oorganisk miljökemi (2005-2014)
Institutionen för kemi (2001-2011)

Ämnesområden

Kemi

Chalmers infrastruktur