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Aspects of reducing agent and role of amine species in the reduction of NO over H-ZSM-5 in oxygen excess

Roberto Matarrese ; Hanna Härelind Ingelsten (Kompetenscentrum katalys (KCK) ; Institutionen för kemi- och bioteknik, Teknisk ytkemi) ; Magnus Skoglundh (Institutionen för kemi- och bioteknik, Teknisk ytkemi ; Kompetenscentrum katalys (KCK))
Journal of Catalysis (0021-9517). Vol. 258 (2008), p. 386-392.
[Artikel, refereegranskad vetenskaplig]

In this study the selective catalytic reduction (SCR) of NO has been investigated over H-ZSM-5 with three different reducing agents. Comparison of the reaction mechanisms using propane, ammonia and isopropylamine has been performed using in situ DRIFTS step-response experiments. The same type of surface NH species, likely organic amines, is formed in the presence of either propane or isopropylamine as reducing agent. For NH3, on the other hand, NH4+ is the dominating NH surface species during reaction. Furthermore, in the case of propane, the nature of the NOx-source, i.e. NO or NO2, is crucial for the reaction. With NO2. the reaction likely proceeds fast via direct reduction, while for NO, oxidation to NO2 is required initially. in either case NH species play a vital role in the SCR reaction and organic amines are possible key-intermediates in the SCR with saturated hydrocarbons over H-ZSM-5.

Nyckelord: H-ZSM-5; lean NO reduction; propane; ammonia; isopropylamine; FTIR



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Denna post skapades 2009-01-23. Senast ändrad 2016-08-15.
CPL Pubid: 88788

 

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Institutioner (Chalmers)

Kompetenscentrum katalys (KCK)
Institutionen för kemi- och bioteknik, Teknisk ytkemi (2005-2014)

Ämnesområden

Energi
Materialvetenskap
Nanovetenskap och nanoteknik
Transport
Hållbar utveckling
Kemi
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