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The lamellar architecture of 1,6-hexamethylenediammonium tetrachlorocobaltate(II)

Amir H. Mahmoudkhani ; Vratislav Langer (Institutionen för oorganisk miljökemi)
Acta Crystallographica, Section E: Structure Reports (ISSN 1600-5368). Vol. E58 (2002), 10, p. m592-m594.
[Artikel, refereegranskad vetenskaplig]

In the title compound, (C6H18N2)[CoCl4], organic dications and inorganic dianions interact with each other through N-H...Cl hydrogen bonds, forming infinite two-dimensional sheets of anions parallel to the ac plane. Alkyl chains act as spacers between these sheets. Only three Cl atoms are involved in hydrogen bonding with ammonium groups. The asymmetric unit consists of one anion together with half of each of two cations on inversion centres.

Nyckelord: X-ray diffraction, hydrogen bonds, lamellar architecture

Denna post skapades 2006-08-29.
CPL Pubid: 3656


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