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Bis(cyanamidonitrato-κN)[tris(3,5-dimethylpyrazole)copper(II)

Jesus Garcia Diaz ; Jozef Kozisek ; Vratislav Langer (Institutionen för oorganisk miljökemi)
Acta Crystallographica, Section E: Structure Reports (ISSN 1600-5368). Vol. E59 (2003), 5, p. m241-m243.
[Artikel, refereegranskad vetenskaplig]

The title compound, [Cu(CN3O2)2(C5H8N2)3], is the first example of a pentacoordinated 3d-central atom involving the cyanamidonitrate ligand. The crystal structure is formed by neutral molecues stabilized by a three-dimensional network consisting of one intramolecular and three intermolecular hydrogen bonds. The Cu atom is pentacoordinated by three N-donor atoms from 3,5-dimethylpyrazole neutral ligands and two N-donor atoms from cyanamidonitrate anions.

Nyckelord: X-ray diffraction, cyanamidonitrate ligand, coordination



Denna post skapades 2006-08-29. Senast ändrad 2007-10-18.
CPL Pubid: 3649

 

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Institutionen för oorganisk miljökemi (1900-2004)

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