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The ortho-to-para ratio of H2Cl+: Quasi-classical trajectory calculations and new simulations in light of new observations

R. Le Gal ; C. Xie ; E Herbst ; D. Talbi ; H. Guo ; Sebastien Muller (Institutionen för rymd-, geo- och miljövetenskap, Onsala rymdobservatorium)
Astronomy and Astrophysics (0004-6361). Vol. 608 (2017), p. A96.
[Artikel, refereegranskad vetenskaplig]

Multi-hydrogenated species with proper symmetry properties can present different spin configurations, and thus exist under different spin symmetry forms, labeled as para and ortho for two-hydrogen molecules. We investigated here the ortho-to-para ratio (OPR) of H2Cl+ in the light of new observations performed in the z = 0.89 absorber toward the lensed quasar PKS 1830−211 with the Atacama Large Millimeter/submillimeter Array (ALMA). Two independent lines of sight were observed, to the southwest (SW) and northeast (NE) images of the quasar, with OPR values found to be 3.15 ± 0.13 and 3.1 ± 0.5 in each region, respectively, in agreement with a spin statistical weight of 3:1. An OPR of 3:1 for a molecule containing two identical hydrogen nuclei can refer to either a statistical result or a high-temperature limit depending on the reaction mechanism leading to its formation. It is thus crucial to identify rigorously how OPRs are produced in order to constrain the information that these probes can provide. To understand the production of the H2Cl+ OPR, we undertook a careful theoretical study of the reaction mechanisms involved with the aid of quasi-classical trajectory calculations on a new global potential energy surface fit to a large number of high-level ab initio data. Our study shows that the major formation reaction for H2Cl+ produces this ion via a hydrogen abstraction rather than a scrambling mechanism. Such a mechanism leads to a 3:1 OPR, which is not changed by destruction and possible thermalization reactions for H2Cl+ and is thus likely to be the cause of observed 3:1 OPR ratios, contrary to the normal assumption of scrambling.

Nyckelord: astrochemistry / ISM: molecules / quasars: individual: PKS 1830 / 211 / galaxies: ISM / quasars: absorption lines / radio lines: galaxies

Denna post skapades 2017-12-15. Senast ändrad 2018-01-17.
CPL Pubid: 253832


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