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Recycling Zinc from Metal Oxide Varistors Through Leaching and Cementation of Cobalt and Nickel

Toni Gutknecht (Institutionen för kemi och kemiteknik, Industriell materialåtervinning) ; Yuda Colombus (Institutionen för kemi och kemiteknik, Industriell materialåtervinning) ; Britt-Marie Steenari (Institutionen för kemi och kemiteknik, Industriell materialåtervinning)
JOURNAL OF SUSTAINABLE METALLURGY (2199-3823). Vol. 3 (2017), 2, p. 239-250.
[Artikel, refereegranskad vetenskaplig]

Metal oxide varistors (MOVs) are housed in a surge arrestor and composed of zinc oxide (> 90 wt%) and other metal oxides such as antimony, bismuth, cobalt, manganese, and nickel. Due to the high concentration of zinc in MOVs, it is a better choice to recycle them as opposed to landfilling. This research set out to determine if cementation could be used as a purification step to remove co-leached metals, leading to a purified leachate suitable for zinc electrowinning. Zinc was leached from crushed MOVs using dilute sulfuric acid, which avoided co-leaching of antimony and bismuth but required further purification to remove co-leached cobalt and nickel. In further purification of the leachate, cementation was investigated. Initial findings suggest that the cobalt concentration can be reduced by over 50 % (200 mg/L) and nickel concentration reduced by over 90 % (90 mg/L), by optimizing the activator (Sb/Cu) concentration, temperature, pH, and surface area of zinc dust. Further investigations into optimized batch addition of zinc and copper-antimony activators verified that nearly 92 % (> 390 mg/L) of the cobalt and all nickel (100 mg/L) can be removed from the acidic varistor leachate. These results suggest that cementation by addition of zinc dust can be used for purification of zinc solutions containing over 400 mg/L cobalt and 100 mg/L nickel and thus preparation of the solutions for zinc electrowinning.

Nyckelord: sulfate solutions, purification, removal, electrolyte, additives, dust

Denna post skapades 2017-08-28.
CPL Pubid: 251462


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Institutioner (Chalmers)

Institutionen för kemi och kemiteknik, Industriell materialåtervinning


Metallurgi och metalliska material

Chalmers infrastruktur

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