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Ruthenium-Catalyzed Azide Alkyne Cycloaddition Reaction: Scope, Mechanism, and Applications

J.R. Johansson ; T. Beke-Somfai ; Anna Said Stålsmeden (Institutionen för kemi och kemiteknik, Organisk kemi) ; Nina Kann (Institutionen för kemi och kemiteknik, Organisk kemi)
Chemical Reviews (0009-2665). Vol. 116 (2016), 23, p. 14726-14768.
[Artikel, refereegranskad vetenskaplig]

The ruthenium-catalyzed azide alkyne cycloaddition (RuAAC) affords 1,5-disubstituted 1,2,3-triazoles in one step and complements the more established copper-catalyzed reaction providing the 1,4-isomer. The RuAAC reaction has quickly found its way into the organic chemistry toolbox and found applications in many different areas, such as medicinal chemistry, polymer synthesis, organocatalysis, supramolecular chemistry, and the construction of electronic devices. This Review discusses the mechanism, scope, and applications of the RuAAC reaction, covering the literature from the last 10 years.

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Denna post skapades 2017-01-10. Senast ändrad 2017-06-28.
CPL Pubid: 246752


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