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Kinetic modeling of C3H6 inhibition on NO Oxidation over Pt Catalyst

muhammad mufti Azis ; Derek Creaser (Institutionen för kemi och kemiteknik, Kemisk reaktionsteknik)
Bulletin of Chemical Reaction Engineering and Catalysis (1978-2993). Vol. 11 (2016), 1, p. 27.
[Artikel, refereegranskad vetenskaplig]

Exhaust after treatment for lean burn and diesel engine is a complex catalytic system that consists of a number of catalytic units. Pt/Al2O3is often used as a model Diesel Oxidation Catalyst (DOC) that plays an important role to facilitate oxidation of NO to NO2. In the present study, we proposed a detailed kinetic model of NO oxidation as well as low temperature C3H6 inhibition to simulate temperatureprogrammed reaction (TPR) data for NO oxidation over Pt/Al2O3. A steady-state microkinetic model based on Langmuir-Hinshelwood mechanism for NO oxidation was proposed. In addition, low temperature C3H6inhibition was proposed as a result of site blocking as well as surface nitrite consumption. The model can explain the experimental data well over the studied temperature range.

Nyckelord: C3H6 inhibition; Doc catalyst; Microkinetic modeling; NO oxidation

Denna post skapades 2016-07-06. Senast ändrad 2016-10-07.
CPL Pubid: 239078


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Institutioner (Chalmers)

Institutionen för kemi och kemiteknik, Kemisk reaktionsteknik



Chalmers infrastruktur