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A redetermination of cis-aquabis(glycinato-κ2N,O)copper(II)

Barbara Casari ; Amir Mahmoudkhani ; Vratislav Langer (Institutionen för oorganisk miljökemi)
Acta Crystallographica Section E: Structure Reports (ISSN 1600-5368). Vol. E60 (2004), 12, p. m1949-m1951.
[Artikel, refereegranskad vetenskaplig]

The crystal structure of the title compound, [Cu(C2H4NO2)2(H2O)], reported by Freeman et al. [(1964). Acta Cryst. 17, 1463-1470], has been reinvestigated and its absolute configuration established by anomalous dispersion effects. The origin of chirality in the crystalline state of this compound is the formation of right-handed helices from a CuII coordination network self-resolved into a pure enantiomeric phase.

Nyckelord: X-ray crystal structure, absolute configuration

Denna post skapades 2006-08-29. Senast ändrad 2007-10-18.
CPL Pubid: 2267


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