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Absolute Asymmetric Synthesis: Protected Substrate Oxidation

Susanne Olsson ; Per Martin Björemark ; Theonitsa Kokoli ; J. Sundberg ; Anders Lennartson (Institutionen för kemi och kemiteknik, Polymerteknologi) ; C. J. McKenzie ; Mikael Håkansson
Chemistry - A European Journal (0947-6539). Vol. 21 (2015), 13, p. 5211-5219.
[Artikel, refereegranskad vetenskaplig]

Three new conglomerates incorporating bidentate sulfide ligands coordinated by Ru-II centers have been prepared. Total spontaneous resolution by slow crystallization gives highly enantioenriched crystal batches, which are used in enantioselective oxidation of the sulfide ligands to give chiral sulfoxide complexes with >98% ee. All relevant stereoisomers have been characterized by single-crystal X-ray diffraction, CD spectroscopy, and chiral HPLC. If the ligand range can be extended to monodentate sulfides, a large-scale and recyclable process for enantioselective oxidation of sulfides can be designed.

Nyckelord: asymmetric synthesis, crystal growth, oxidation, ruthenium, sulfur ligands



Denna post skapades 2015-05-11. Senast ändrad 2015-05-26.
CPL Pubid: 216944

 

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Institutioner (Chalmers)

Institutionen för kemi och molekylärbiologi (GU)
Institutionen för kemi och kemiteknik, Polymerteknologi

Ämnesområden

Oorganisk kemi

Chalmers infrastruktur