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Low temperature and cost-effective growth of vertically aligned carbon nanofibers using spin-coated polymer-stabilized palladium nanocatalysts

Amin M Saleem (Institutionen för mikroteknologi och nanovetenskap, Bionanosystem) ; S. Shafiee ; T. Krasia-Christoforou ; I. Savva ; Gert Göransson ; V. Desmaris ; Peter Enoksson (Institutionen för mikroteknologi och nanovetenskap, Bionanosystem)
Science and Technology of Advanced Materials (1468-6996). Vol. 16 (2015), 1, p. artikel nr 015007.
[Artikel, refereegranskad vetenskaplig]

We describe a fast and cost-effective process for the growth of carbon nanofibers (CNFs) at a temperature compatible with complementary metal oxide semiconductor technology, using highly stable polymer-Pd nanohybrid colloidal solutions of palladium catalyst nanoparticles (NPs). Two polymer-Pd nanohybrids, namely poly(lauryl methacrylate)-block-poly((2-acetoacetoxy) ethyl methacrylate)/Pd (LauMA(x)-b-AEMA(y)/Pd) and polyvinylpyrrolidone/Pd were prepared in organic solvents and spin-coated onto silicon substrates. Subsequently, vertically aligned CNFs were grown on these NPs by plasma enhanced chemical vapor deposition at different temperatures. The electrical properties of the grown CNFs were evaluated using an electrochemical method, commonly used for the characterization of supercapacitors. The results show that the polymer-Pd nanohybrid solutions offer the optimum size range of palladium catalyst NPs enabling the growth of CNFs at temperatures as low as 350 degrees C. Furthermore, the CNFs grown at such a low temperature are vertically aligned similar to the CNFs grown at 550 degrees C. Finally the capacitive behavior of these CNFs was similar to that of the CNFs grown at high temperature assuring the same electrical properties thus enabling their usage in different applications such as on-chip capacitors, interconnects, thermal heat sink and energy storage solutions.

Nyckelord: polymer-stabilized nanoparticles, carbon nanofibers, low temperature growth, cost effective



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Denna post skapades 2015-05-07. Senast ändrad 2015-07-15.
CPL Pubid: 216723

 

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Institutioner (Chalmers)

Institutionen för mikroteknologi och nanovetenskap, Bionanosystem (2007-2015)
Institutionen för kemi och molekylärbiologi (GU)

Ämnesområden

Energi
Nanovetenskap och nanoteknik
Produktion
Transport
Innovation och entreprenörskap (nyttiggörande)
Biologiska vetenskaper

Chalmers infrastruktur

NFL/Myfab (Nanofabrication Laboratory)

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