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2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; Structure and reactions with catechols and PtCl2(PR(3))(2) (R=Et or Bu(II))

Mark Foreman (Institutionen för kärnkemi) ; A. M. Z. Slawin ; J. D. Woollins
Journal of the Chemical Society-Dalton Transactions (0300-9246). 18, p. 3653-3657. (1996)
[Artikel, refereegranskad vetenskaplig]

Reaction of ferrocene (or 1,1'-dimethylferrocene) with P4S10 yielded R'P(S)S2P(S)R' (R' = ferrocenyl) (or the analogous dimethylferrocene species). This compound reacted with catechols to form R'P(S)O2C2 ring systems and with [PtCl2(PR(3))(2)] (R = Et or Bu(II)) to give [R'PS3Pt(PR(3))(2)]. The new compounds have been characterised spectroscopically with illustrative examples having been fully studied by X-ray crystallography.



Denna post skapades 2014-08-30. Senast ändrad 2015-07-28.
CPL Pubid: 202133

 

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Institutionen för kärnkemi (1960-2002)

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