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Faradaic efficiency of O-2 evolution on metal nanoparticle sensitized hematite photoanodes

Beniamino Iandolo (Institutionen för teknisk fysik, Kemisk fysik) ; Björn Wickman (Institutionen för teknisk fysik, Kemisk fysik) ; B. Seger ; I. Chorkendorff ; Igor Zoric (Institutionen för teknisk fysik, Kemisk fysik) ; Anders Hellman (Institutionen för teknisk fysik, Kemisk fysik)
Physical Chemistry Chemical Physics (1463-9076). Vol. 16 (2014), 3, p. 1271-1275.
[Artikel, refereegranskad vetenskaplig]

Functionalization of transition metal oxides using metallic nanoparticles is an interesting route towards efficient photoelectrochemical hydrogen production via water splitting. Although an enhanced photocurrent in photoanodes upon functionalization with metallic nanostructures has been observed in several studies, to the best of our knowledge no measurements of the Faradaic efficiency (FE) of the oxygen evolution reaction (OER) have been reported for such systems. This work characterizes the FE on a model system consisting of ultra-thin films of hematite (Fe2O3) sensitized with Ti/Au nanodisks. Compared to bare hematite references, sensitized samples showed significantly enhanced photocurrents as well as O-2 evolution. Experimental evidence suggests that the observed enhancement was not due to photocatalytic activity of the nanodisks. The FE has been determined to be 100%, within the experimental errors, for both sensitized and reference samples. Also, this work demonstrates that the sensitized samples were stable for at least 16 hours photocurrent testing. The concepts shown in this work are generally applicable to any situation in which a semiconductor has its water splitting performance enhanced by metallic nanostructures.

Nyckelord: ATOMIC LAYER DEPOSITION, SEMICONDUCTOR ELECTRODES, WATER OXIDATION, IRON-OXIDE, HYDROGEN-PRODUCTION, SOLAR, PHOTOELECTRODES, ABSORPTION, CATALYST, FILMS



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Denna post skapades 2014-01-17. Senast ändrad 2015-03-30.
CPL Pubid: 192774

 

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Institutioner (Chalmers)

Institutionen för teknisk fysik, Kemisk fysik (1900-2015)

Ämnesområden

Energi
Materialvetenskap
Nanovetenskap och nanoteknik
Transport
Fysik
Kemi

Chalmers infrastruktur

NFL/Myfab (Nanofabrication Laboratory)