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2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; Structure and reactions with catechols and [PtCl2(PR(3))(2)] (R=Et or Bu(II))

Mark Foreman (Institutionen för kärnkemi) ; J.Derek Woollins ; Alex.M.Z. Slawin
Journal of the Chemical Society. Dalton Transactions (1472-7773). 18, p. 3653-3657. (1996)
[Artikel, refereegranskad vetenskaplig]

Reaction of ferrocene (or 1,1'-dimethylferrocene) with P4S10 yielded R'P(S)S2P(S)R' (R' = ferrocenyl) (or the analogous dimethylferrocene species). This compound reacted with catechols to form R'P(S)O2C2 ring systems and with [PtCl2(PR(3))(2)] (R = Et or Bu(II)) to give [R'PS3Pt(PR(3))(2)]. The new compounds have been characterised spectroscopically with illustrative examples having been fully studied by X-ray crystallography.

Nyckelord: X-RAY STRUCTURE; LAWESSONS REAGENT



Denna post skapades 2013-05-22. Senast ändrad 2015-07-28.
CPL Pubid: 177195

 

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