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Microwaves as a synthetic route for preparing electrochemically active TiO2 nanoparticles

Damien Monti (Institutionen för teknisk fysik, Kondenserade materiens fysik) ; A. Ponrouch ; M. Estruga ; M. R. Palacin ; J. A. Ayllon ; A. Roig
Journal of Materials Research (0884-2914). Vol. 28 (2013), 3, p. 340-347.
[Artikel, refereegranskad vetenskaplig]

Nanocrystalline anatase was synthesized, using both domestic and laboratory microwave ovens, from different precursors. Nanoparticulate anatase was obtained after microwave irradiation of tetra-butyl orthotitanate solution in benzyl alcohol. As-synthesized samples have orange color due to the presence of organics that were eliminated after annealing at 500 degrees C, whereas the size of small anatase nanocrystals (around 8 nm) was preserved. Other nanocrystalline anatase samples were obtained from hexafluorotitanate-organic salt ionic liquid-like precursors. In this case, use of a domestic microwave oven and very short processing times (1-3 min irradiation time) were involved. Good specific capacity values and capacity retention at high C rates for insertion/deinsertion of Li+ were recorded when testing such nanoparticles as electrode material in lithium cells. The electrochemical performances were found be strongly dependent on the phase composition, which in turn could be tuned through the synthetic procedure.

Nyckelord: versatile reaction system, lithium-ion battery, titanium-dioxide, low-temperature, assisted synthesis, oxide nanoparticles, powder, diffraction, storage properties, facile synthesis, benzyl alcohol

Denna post skapades 2013-03-01. Senast ändrad 2013-04-03.
CPL Pubid: 174302


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Institutionen för teknisk fysik, Kondenserade materiens fysik (1900-2015)



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