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Bridging nitrile groups in a metal-organic framework

Anders Lennartson (Institutionen för kemi- och bioteknik, Polymerteknologi) ; C. J. McKenzie
Journal of Coordination Chemistry (0095-8972). Vol. 65 (2012), 23, p. 4194-4202.
[Artikel, refereegranskad vetenskaplig]

This article describes two coordination polymers based on sodium and nickel triflates, respectively, and the linker adiponitrile (1,4-butanedinitrile). Sodium triflate forms a coordination network with adiponitrile, where the nitriles bridge the sodium ions, a rare coordination mode for a nitrile. Crystal structures of alkali metal complexes of linear aliphatic dinitriles have not been reported previously. With nickel triflate, a cationic 1-D coordination polymer results upon coordination of adiponitrile.

Nyckelord: Dinitrile, Coordination polymer, MOF, crystal-structure, molecular-structure, complex, coordination, ligand, acetonitrile, chloride



Denna post skapades 2012-12-12. Senast ändrad 2016-08-22.
CPL Pubid: 167571

 

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Institutioner (Chalmers)

Institutionen för kemi- och bioteknik, Polymerteknologi (2005-2014)

Ämnesområden

Kemi

Chalmers infrastruktur