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Replacement of H-bonded bridged water by transition metal ions in poly(1-vinylimidazole-co-methylmethacrylate) copolymers: A vibrational spectroscopy study using mid-FTIR, far-FTIR and ab initio calculations

Markus Andersson Trojer (Institutionen för kemi- och bioteknik, Teknisk ytkemi ; SuMo Biomaterials) ; Anders Mårtensson (Institutionen för kemi- och bioteknik, Polymerteknologi) ; Magnus Nydén (Institutionen för kemi- och bioteknik, Teknisk ytkemi ; SuMo Biomaterials)
Vibrational Spectroscopy (0924-2031). Vol. 61 (2012), p. 38-42.
[Artikel, refereegranskad vetenskaplig]

A detailed structural analysis of the vibrational spectra of hydrophobic PVM (poly(1-vinylimidazole-co-methylmethacrylate)) copolymers PVM-4 (4 wt% 1-VIm) and PVM-44 (44 wt% 1-VIm) is provided with respect to bridging water and subsequent replacement by bridging transition metal ions. PVM-44 (44 wt% 1-VIm) with a high fraction of 1-VIm forms water bridges as evident by the water bending vibration, which is shifted up to 1665 cm(-1). This band vanishes as transition metal ions are introduced and a new band at 952 cm(-1) appears which is ascribed as a delta(ring) band involving the entire [M(Im)(n)](2+) unit. This fact is affirmed using ab initio calculations. The transition metal ions coordinate exclusively the imidazole groups. Although the imidazole associated water is replaced by transition metal ions, the amount of sorbed water for the very hydrophobic PVM-4 is increased as indicated by the nu(OH) region.

Nyckelord: Bridged water, Methyl methacrylate, B3LYP hybrid functional, 1-, imidazole complexes, containing polymers, chelating resins, spectra, coordination, chemistry, histidine, coatings, monomers, release

Denna post skapades 2012-06-28. Senast ändrad 2016-04-22.
CPL Pubid: 159748


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Institutioner (Chalmers)

Institutionen för kemi- och bioteknik, Teknisk ytkemi (2005-2014)
SuMo Biomaterials
Institutionen för kemi- och bioteknik, Polymerteknologi (2005-2014)



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