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Effect of Lithium Salt on the Stability of Dispersions of Fumed Silica in the Ionic Liquid BMImBF4

Jonas Nordström (Institutionen för teknisk fysik, Kondenserade materiens fysik) ; Luis Antonio Aguilera Medina (Institutionen för teknisk fysik, Kondenserade materiens fysik) ; Aleksandar Matic (Institutionen för teknisk fysik, Kondenserade materiens fysik)
Langmuir (0743-7463). Vol. 28 (2012), 9, p. 4080-4085.
[Artikel, refereegranskad vetenskaplig]

We have investigated the stability and the interactions in dispersions of colloidal fumed silica, Aerosil 200, and the ionic liquid 1-butyl-3-methylimidazolium tetraflouroborate (BMImBF4) as a function of Li-salt concentration (LiBF4). Photon correlation spectroscopy was used to study the aggregation behavior at low silica concentration and Raman spectroscopy was used to investigate the interactions in the ionic liquid and with the silica surface. We find that the addition of LiBF4 increases the stability of the dispersions, with smaller agglomerates of silica particles and higher gelation concentrations in the presence of Li-salt. The increased stability with the addition of Li-salt is explained by the formation of a more stable solvation layer, where Li-ions accumulate on the surface. This leads to an increased interaction between lithium ions and the BF4- anions in the solvation layer as seen by Raman spectroscopy. Upon gelation the Li-ions are expelled from the surface as hydrogen bonding between the silica particles are formed. For both neat BMImBF4 and Li-salt doped BMImBF4/silica dispersions a weak gel phase was found preceding the formation of a strong gel at slightly higher silica concentrations.

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Denna post skapades 2012-02-24. Senast ändrad 2015-12-17.
CPL Pubid: 155405


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Institutioner (Chalmers)

Institutionen för teknisk fysik, Kondenserade materiens fysik (1900-2015)


Den kondenserade materiens fysik
Yt- och kolloidkemi

Chalmers infrastruktur

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