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Reference mass spectra of hexoses and methylated hexoses

Trimethylsilyl derivatives

Göran Petersson (Institutionen för teknisk kemi)
Archives of Mass Spectral Data Vol. 1 (1970), p. 624-665.
[Artikel, refereegranskad vetenskaplig]

Certified mass spectra (70 eV) as tables of relative abundance and as bar graphs are given for trimethylsilyl derivatives of aldohexoses. From specific fragment ions, the number and position of O-methyl groups can be assessed for unknown methylated hexoses as outlined in a previous article (link).

Nyckelord: monosaccharides, aldoses, methyl groups, Me3Si derivatives, GC - MS, structure determination

Publication was invited by professor Einar Stenhagen. Together with professor Sixten Abrahamsson and the legendary professor Fred McLafferty he started up Archives of Mass Spectral Data as an early effert to collect high-quality reference spectra.

The spectra of hexoses were also included in the PhD thesis of Göran Petersson

Denna post skapades 2012-01-17.
CPL Pubid: 153425


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Institutionen för teknisk kemi (1946-1998)



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