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Molecular characterization of hydrolyzed cationized nanocrystalline cellulose, cotton cellulose and softwood kraft pulp using high resolution 1D and 2D NMR

Hanna de la Motte (Institutionen för kemi- och bioteknik, Organisk kemi) ; Merima Hasani (Institutionen för kemi- och bioteknik, Organisk kemi) ; Harald Brelid (Institutionen för kemi- och bioteknik, Skogsindustriell kemiteknik) ; Gunnar Westman (Institutionen för kemi- och bioteknik, Organisk kemi)
Carbohydrate Polymers (0144-8617). Vol. 85 (2011), 4, p. 738-746.
[Artikel, refereegranskad vetenskaplig]

Nanocrystalline cellulose, cotton linters and softwood kraft pulp were reacted with the cationic epoxide 2,3-epoxypropyltrimethyl ammonium chloride (EPTMAC) according to two different procedures, whereof one was a solvent and reagent minimizing spray technique. The samples were subjected to acid hydrolysis and characterized by solution-state nuclear magnetic resonance (NMR). The spectra were obtained using a 600 MHz cryoprobe NMR instrument. The use of ion exchange SPE-column chromatography enhanced the intensity of the peaks derived from the modified monosaccharide residues and opened for detailed NMR characterization at low degrees of substitution. In addition to a consistent 9 ppm change in the initial shifts of carbons adjacent to substituted hydroxyl groups, the NMR spectra proved that other neighboring atoms were affected by the substitution. Unlike nanocrystalline cellulose and cotton cellulose, the softwood kraft pulp cationized with the spray technique demonstrated a higher preference for 0-6 (83%), on the expense of O-2 substitution (16%).

Nyckelord: Softwood kraft pulp, Cotton linters, Nanocrystalline cellulose, 2D NMR, Cationization, Characterization, substitution patterns, chemical-shifts, derivatives, starch, functionalization, polysaccharides, spectroscopy, chloride, h-1-nmr, fiber



Denna post skapades 2011-07-05. Senast ändrad 2016-02-01.
CPL Pubid: 143102

 

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Institutioner (Chalmers)

Institutionen för kemi- och bioteknik, Organisk kemi (2006-2014)
Institutionen för kemi- och bioteknik, Skogsindustriell kemiteknik (2005-2014)

Ämnesområden

Polymerkemi

Chalmers infrastruktur